A few notes about present perfect and past perfect may help here.
1. Think of present perfect as a tense that
connects the present and the past. It may be that the event is still true 'I've lived in NYC for 2 years.', or that it's recent 'I've just won the competition!', or that we can see the results 'What have you been doing?'. There are several kinds of relationship going on here.
2. Think of past perfect as the
past before the past. It's a really useful tense for making the order of past events clear. Compare 'When I arrived, they had eaten dinner.' with 'When I arrived, they ate dinner.' However, if the order is already clear, then we don't need to use it. For example, 'He was crying because he lost his toy.' is totally fine, although 'He was crying because he had lost his toy.' is also fine.
3. Note that the deciding factor is the
meaning of the sentence: tenses, like all grammar, exist so that we can communicate effectively. Rules can help us out here, but don't be a slave to a rule if it doesn't fit the situation.
Applying these thoughts to those problems, note that the ozone problem doesn't give you a choice between 'had appeared' and simply 'appeared'. Here, the 'had' emphasizes that the appearing took place before the realization, but I think 'appeared' would be fine also. It's not that common to use past perfect for an event before present perfect. The more common pairing is past perfect and past simple.
As for the second one, the phrase 'Art historians have suggested that Impressionism...' means that some suggested in the past, but the suggestion is still going on. I can't find any other logical relationship between the past and the present for this context. It might as well say, 'Some art historians suggest that Impressionism...'. Consequently, we don't have a second past event to use with the past perfect.
Here "have suggested" also seems to be a point event.
Not sure exactly what you mean by 'point event', but if you mean 'action that took place in the past and is now finished' then we'd need to use the past simple. If we wanted to state that the suggesting took place in the past and is finished now, we'd need to say 'Some art historians once suggested that Impressionism...'.